Electron‐Sponge Behavior, Reactivity and Electronic Structures of Cobalt‐Centered Cubic Co9Te6(CO)8 Clusters (Eur. J. Inorg. Chem. 12/2008)
Identifieur interne : 000768 ( Main/Exploration ); précédent : 000767; suivant : 000769Electron‐Sponge Behavior, Reactivity and Electronic Structures of Cobalt‐Centered Cubic Co9Te6(CO)8 Clusters (Eur. J. Inorg. Chem. 12/2008)
Auteurs : Mustapha Bencharif [Algérie] ; Olivier Cador [France] ; Hélène Cattey [France] ; Alexander Ebner [Allemagne] ; Jean-François Halet [France] ; Samia Kahlal [France] ; Walter Meier [Allemagne] ; Yves Mugnier [France] ; Jean-Yves Saillard [France] ; Patrick Schwarz [Allemagne] ; Fatima Zohra Trodi [Algérie, France] ; Joachim Wachter [Allemagne] ; Manfred Zabel [Allemagne]Source :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2008-04.
Descripteurs français
- Wicri :
- topic : Cobalt, électrochimie.
English descriptors
- KwdEn :
Abstract
The cover picture shows an organometallic electron sponge and an elephant‐ear sponge in the background (photo by F. and J. Burek, National Marine Sanctuaries). The electronic flexibility of the cobalt‐centered cubic [Co9Te6(CO)8]n cluster ([3]n) in the central circle is expressed by differently charged states (n = 1+ to 5–). Starting from the upper left corner of our graphic in a clockwise direction, neutral [Co9Te6(CO)4(PPh3)4], structurally diverse networks of [Ph3PNPPh3][3] and [Ph3PNPPh3]2[3] salts and the core of the [Co9Te3{ν5‐Cp′2Nb(CO)Te}3(CO)8] cluster as a pseudo‐protonated representative of the [3]3– anion are shown. Details of the structural, electrochemical and theoretical properties of these compounds are described in the article by J. Wachter et al. on page 1959 ff.
Url:
- https://api.istex.fr/document/856B23C0365D0A1A346E29FFB55A1D1CB7B9C7EE/fulltext/pdf
- https://api.istex.fr/document/A3880727306C37B2B0BB6632BAD51CE31A841019/fulltext/pdf
DOI: 10.1002/ejic.200890029
Affiliations:
- Algérie, Allemagne, France
- Bourgogne, Bourgogne-Franche-Comté, Région Bretagne
- Dijon, Rennes
- Université de Rennes 1
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Le document en format XML
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Joachim" sort="Wachter, Joachim" uniqKey="Wachter J" first="Joachim" last="Wachter">Joachim Wachter</name><affiliation wicri:level="1"><country xml:lang="fr">Allemagne</country><wicri:regionArea>Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg</wicri:regionArea><wicri:noRegion>93040 Regensburg</wicri:noRegion><wicri:noRegion>93040 Regensburg</wicri:noRegion></affiliation><affiliation wicri:level="1"><country wicri:rule="url">Allemagne</country></affiliation></author><author><name sortKey="Zabel, Manfred" sort="Zabel, Manfred" uniqKey="Zabel M" first="Manfred" last="Zabel">Manfred Zabel</name><affiliation wicri:level="1"><country xml:lang="fr">Allemagne</country><wicri:regionArea>Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg</wicri:regionArea><wicri:noRegion>93040 Regensburg</wicri:noRegion><wicri:noRegion>93040 Regensburg</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j">European Journal of Inorganic Chemistry</title><title level="j" type="abbrev">Eur. J. Inorg. Chem.</title><idno type="ISSN">1434-1948</idno><idno type="eISSN">1099-0682</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2008-04">2008-04</date><biblScope unit="volume">2008</biblScope><biblScope unit="issue">12</biblScope><biblScope unit="page" from="1943">1943</biblScope><biblScope unit="page" to="1943">1943</biblScope></imprint><idno type="ISSN">1434-1948</idno></series><idno type="istex">856B23C0365D0A1A346E29FFB55A1D1CB7B9C7EE</idno><idno type="DOI">10.1002/ejic.200890029</idno><idno type="ArticleID">EJIC200890029</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1434-1948</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cluster</term><term>Cobalt</term><term>Electrochemistry</term><term>Electronic structure</term><term>Tellurium</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Cobalt</term><term>électrochimie</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract">The cover picture shows an organometallic electron sponge and an elephant‐ear sponge in the background (photo by F. and J. Burek, National Marine Sanctuaries). The electronic flexibility of the cobalt‐centered cubic [Co9Te6(CO)8]n cluster ([3]n) in the central circle is expressed by differently charged states (n = 1+ to 5–). Starting from the upper left corner of our graphic in a clockwise direction, neutral [Co9Te6(CO)4(PPh3)4], structurally diverse networks of [Ph3PNPPh3][3] and [Ph3PNPPh3]2[3] salts and the core of the [Co9Te3{ν5‐Cp′2Nb(CO)Te}3(CO)8] cluster as a pseudo‐protonated representative of the [3]3– anion are shown. Details of the structural, electrochemical and theoretical properties of these compounds are described in the article by J. Wachter et al. on page 1959 ff.</div></front></TEI><affiliations><list><country><li>Algérie</li><li>Allemagne</li><li>France</li></country><region><li>Bourgogne</li><li>Bourgogne-Franche-Comté</li><li>Région Bretagne</li></region><settlement><li>Dijon</li><li>Rennes</li></settlement><orgName><li>Université de Rennes 1</li></orgName></list><tree><country name="Algérie"><noRegion><name sortKey="Bencharif, Mustapha" sort="Bencharif, Mustapha" uniqKey="Bencharif M" first="Mustapha" last="Bencharif">Mustapha Bencharif</name></noRegion><name sortKey="Trodi, Fatima Zohra" sort="Trodi, Fatima Zohra" uniqKey="Trodi F" first="Fatima Zohra" last="Trodi">Fatima Zohra Trodi</name></country><country name="France"><region name="Région Bretagne"><name sortKey="Cador, Olivier" sort="Cador, Olivier" uniqKey="Cador O" first="Olivier" last="Cador">Olivier Cador</name></region><name sortKey="Cattey, Helene" sort="Cattey, Helene" uniqKey="Cattey H" first="Hélène" last="Cattey">Hélène Cattey</name><name sortKey="Halet, Jean Rancois" sort="Halet, Jean Rancois" uniqKey="Halet J" first="Jean-François" last="Halet">Jean-François Halet</name><name sortKey="Kahlal, Samia" sort="Kahlal, Samia" uniqKey="Kahlal S" first="Samia" last="Kahlal">Samia Kahlal</name><name sortKey="Mugnier, Yves" sort="Mugnier, Yves" uniqKey="Mugnier Y" first="Yves" last="Mugnier">Yves Mugnier</name><name sortKey="Saillard, Jean Ves" sort="Saillard, Jean Ves" uniqKey="Saillard J" first="Jean-Yves" last="Saillard">Jean-Yves Saillard</name><name sortKey="Trodi, Fatima Zohra" sort="Trodi, Fatima Zohra" uniqKey="Trodi F" first="Fatima Zohra" last="Trodi">Fatima Zohra Trodi</name></country><country name="Allemagne"><noRegion><name sortKey="Ebner, Alexander" sort="Ebner, Alexander" uniqKey="Ebner A" first="Alexander" last="Ebner">Alexander Ebner</name></noRegion><name sortKey="Meier, Walter" sort="Meier, Walter" uniqKey="Meier W" first="Walter" last="Meier">Walter Meier</name><name sortKey="Schwarz, Patrick" sort="Schwarz, Patrick" uniqKey="Schwarz P" first="Patrick" last="Schwarz">Patrick Schwarz</name><name sortKey="Wachter, Joachim" sort="Wachter, Joachim" uniqKey="Wachter J" first="Joachim" last="Wachter">Joachim Wachter</name><name sortKey="Wachter, Joachim" sort="Wachter, Joachim" uniqKey="Wachter J" first="Joachim" last="Wachter">Joachim Wachter</name><name sortKey="Zabel, Manfred" sort="Zabel, Manfred" uniqKey="Zabel M" first="Manfred" last="Zabel">Manfred Zabel</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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